Product Identification
【Product Name】1-Methyl-1H-pyrrole
【Synonyms】N-Methylpyrrole ；N-甲基吡咯
【CAS】96-54-8
【Formula】C5H7N
【Molecular Weight】81.12
【EINECS】202-513-7
【RTECS】UX9640000
【RTECS Class】Mutagen
【Beilstein/Gmelin】104181
【Beilstein Reference】5-20-05-00008
【EC Class】highly flammable, harmful, irritant
Physical and Chemical Properties
【Appearance】Pale yellow to brown liquid with an amine-like odor.
【Solubility in water】10 g/L
【Melting Point】-57℃
【Boiling Point】112℃
【Vapor Pressure】17 (20℃)
【Density】0.9145 g/cm3 (15℃)
【Heat Of Vaporization】407.1 kJ/mol
【Vapor Density】2.8
【Refractive Index】1.4875 (20℃)
First Aid Measures
【Ingestion】If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and Storage
【Storage】Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.
【Handling】Wash thoroughly after handling. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Use with adequate ventilation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or flames.
Hazards Identification
【Ingestion】May cause irritation of the digestive tract.
【Inhalation】Causes severe respiratory tract irritation. Vapors may cause dizziness or suffocation.
【Skin】Causes skin irritation.
【Eyes】May cause eye irritation.
【Hazards】Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will sp along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】R 11 22 36/37/38
【EC Safety Phrase】S 16 26 36/37/39
【UN (DOT)】1993
Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Poison Class】3
Fire Fighting Measures
【Flash Point】16℃
【Autoignition】400℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be sp by the use of water. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. This material is lighter than water.
【Upper exp. limit】8.5
【Lower exp. limit】1.4
【Fire Potential】Flammable Liquid.
Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.
Stability and Reactivity
【Disposal Code】5
【Incompatibilities】Acids, acid chlorides, acid anhydrides, carbon dioxide, strong oxidizing agents.
【Stability】Stable under normal temperatures and pressures.
【Decomposition】Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.
Transport Information
【UN Number】1993
【Hazard Class】3
【Packing Group】I; II; III
【HS Code】2933 99 90