氟硅唑安全技术说明书
Product Identification
【Product Name】1-((Bis(4-fluorophenyl)methylsilyl)methyl)-1H-1,2,4-triazole
【Synonyms】Benocarp
【CAS】85509-19-9
【Formula】C16H15F2N3Si
【Molecular Weight】315.39999999999998
【RTECS】XZ4105000
【Merck】12,4240
【Beilstein/Gmelin】5824097
【Beilstein Reference】6-26
【EC Index Number】014-017-00-6

Physical and Chemical Properties
【Appearance】Light brown granules with a slight odor.
【Solubility in water】Insoluble
【Melting Point】54
【Boiling Point】393
【Vapor Pressure】2.3E-6 (25 C)
【Density】1.17 g/cm3
【pKa/pKb】11.98 (pKb)
【Partition Coefficient】3.84
【Heat Of Vaporization】64.22 kJ/mol
【Usage】Agricultural fungicide.

First Aid Measures
【Ingestion】If swallowed, seek medical attention. Never give anything by mouth to an unconscious person.
【Inhalation】If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek medical attention.
【Skin】In case of contact, immediately wash skin with soap and plenty of water. Wash contaminated clothing before reuse.
【Eyes】In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Seek Medical attention.

Handling and Storage
【Storage】Store in closed original containers in a cool, well ventilated area out of direct sunlight. Keep container tightly closed.

Hazards Identification
【Inhalation】May irritate the throat. Not classified as a respiratory irritant according to the criteria of NOHSC.
【Skin】May irritate skin, slightly toxic by contact. Classified as a skin irritant but not a skin sensitiser.
【Eyes】Classified as an eye irritant according to NOHSC. Attacks eyes. Causes substantial but temporary eye injury.
【Ingestion】Slightly toxic by ingestion. Not classified as hazardous by inhalation according to the criteria of NOHSC.
【EC Risk Phrase】R: 36 38 40 51/53 61
【EC Safety Phrase】S: 26 35 36/37 45 53 57

Fire Fighting Measures
【Flash Point】191
【Autoignition】525
【Lower exp. limit】.17
【Fire Potential】Not a fire or explosion hazard. Like most organic powders or crystals, under severe dusting conditions, this material may form explosive mixtures in air. Wear self-contained breathing apparatus and full protective equipment. Suitable extinguishing media: water spray, dry powder, foam, carbon dioxide (CO2). On small fires, if area is heavily exposed to fire and if conditions permit, let fire burn itself out since water may increase the contamination hazard.

Accidental Release Measures
【Small spills/leaks】Shovel or sweep up. Never return to container for reuse. Scoop into bags or boxes with plastic or aluminium shovel.

Stability and Reactivity
【Stability】Stable at normal temperatures and storage conditions.
【Combustion Products】There is a possibility of generating hazardous gases during a fire due to presence of F and CN groups, but material will not burn virously.

Exposure Controls/Personal Protection
【Exposure Effects】Safety ggles and/or face shield, gloves and work clothing.
【Poison Class】4