Product Identification
【Product Name】Trimethylsilyl azide
【Synonyms】叠氮基三甲基硅烷
【CAS】4648-54-8
【Formula】C3H9N3Si
【Molecular Weight】115.21
【EINECS】225-078-5
【Beilstein/Gmelin】1903730
【EC Class】highly flammable, toxic
Physical and Chemical Properties
【Appearance】Clear, colorless liquid.
【Solubility in water】Decomposition
【Melting Point】-95℃
【Boiling Point】52℃
【Density】0.8763 g/cm3 (20℃)
【Vapor Density】3.97
【Refractive Index】1.41 (20℃)
First Aid Measures
【Ingestion】Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and Storage
【Storage】Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. Refrigerator (approx 4 C). Store protected from moisture.
【Handling】Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Do not allow contact with water. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or flames. Keep from contact with moist air and steam.
Hazards Identification
【Inhalation】Causes respiratory tract irritation. Vapors may cause dizziness or suffocation. Can produce delayed pulmonary edema. Harmful if inhaled. May cause burning sensation in the chest.
【Skin】Causes skin irritation. Harmful if absorbed through the skin. May cause cyanosis of the extremities.
【Eyes】Causes eye irritation. May cause chemical conjunctivitis and corneal damage.
【Ingestion】Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of large amounts may cause CNS depression.
【Hazards】Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will sp along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers.
【EC Risk Phrase】R 11 23/24/25
【EC Safety Phrase】S 16 23 36/37 45
【UN (DOT)】2929
Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】Prolonged or repeated skin contact may cause dermatitis. Effects may be delayed.
Fire Fighting Measures
【Flash Point】6℃
【Autoignition】>300℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be sp by the use of water. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT get water inside containers.
【Fire Potential】HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Do not get water inside containers. A vapor suppressing foam may be used to reduce vapors.
Stability and Reactivity
【Disposal Code】9
【Incompatibilities】Moisture, strong oxidizing agents, strong acids.
【Stability】Stable at room temperature in closed containers under normal storage and handling conditions.
【Decomposition】Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen, silicon oxide.
【Combustion Products】Fire will produce irritating, corrosive and/or toxic gases.
Transport Information
【UN Number】2929
【Hazard Class】6.1
【Packing Group】I; II
【HS Code】2931 00 95