Product Identification
【Product Name】2-Thiopheneacetyl chloride
【Synonyms】2-噻吩乙酰氯
【CAS】39098-97-0
【Formula】C6H5ClOS
【Molecular Weight】160.62
【EINECS】254-290-0
【Beilstein/Gmelin】114547
【Beilstein Reference】4-18-00-04063
【EC Class】corrosive
Physical and Chemical Properties
【Appearance】A clear yellow to dark brown liquid.
【Boiling Point】130℃
【Density】1.3 g/cm3
【Vapor Density】5.54
【Refractive Index】1.55 (20℃)
First Aid Measures
【Ingestion】Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. Do not use mouth-to-mouth respiration if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
【Skin】Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and Storage
【Storage】Keep container closed when not in use. Corrosives area. Refrigerator (approx 4 C). Store protected from moisture.
【Handling】Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Use and store under nitrogen. Do not allow contact with water. Use only in a chemical fume hood. Discard contaminated shoes. Keep from contact with moist air and steam. Do not breathe vapors.
Hazards Identification
【Inhalation】Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. May cause systemic effects. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.
【Skin】Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
【Eyes】Causes eye burns. May cause chemical conjunctivitis and corneal damage.
【Ingestion】May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause systemic effects.
【Hazards】When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】R 34
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】3265
Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】Effects may be delayed.
Fire Fighting Measures
【Flash Point】101℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Water hydrolyzes material liberating acidic gas which in contact with metal surfaces can generate flammable and/or explosive hydrogen gas. Extinguishing media: Do NOT use water directly on fire. Use foam, dry chemical, or carbon dioxide. Do NOT get water inside containers.
【Fire Potential】Combustible material: may burn but does not ignite ily.
Accidental Release Measures
【Small spills/leaks】Clean up spills immediately, using the appropriate protective equipment. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Provide ventilation. Do not get water inside containers.
Stability and Reactivity
【Stability】Stable under normal temperatures and pressures. May decompose on exposure to moist air or water. Moisture sensitive.
【Incompatibilities】Strong oxidizing agents, strong bases, moisture.
【Decomposition】Hydrogen chloride, carbon monoxide, oxides of sulfur, carbon dioxide.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.
Transport Information
【UN Number】3265
【Hazard Class】8
【Packing Group】I; II; III
【HS Code】2934 99 90