包装危险货物技术说明书：参见R-(+)-α-甲基苄胺.doc

Product Identification
【Product Name】(R)-(+)-1-Phenylethylamine R(+)-1-苯乙胺
【Synonyms】D-alpha-Methylbenzylamine
【CAS】3886-69-9
【Formula】C8H11N
【Molecular Weight】121.18
【EINECS】223-423-4
【Merck】12,6106
【Beilstein/Gmelin】2410916
【Beilstein Reference】4-12-00-02424
【EC Class】harmful, corrosive

Physical and Chemical Properties
【Appearance】Clear, colorless liquid.
【Solubility in water】40 g/L (20 C)
【Melting Point】32.5
【Boiling Point】180
【Vapor Pressure】30 (20 C)
【Density】0.9561 g/cm3 (15 C)
【Heat Of Vaporization】54.47 kJ/mol
【Refractive Index】1.53 (20 C)

First Aid Measures
【Ingestion】If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed.

Handling and Storage
【Storage】Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
【Handling】Wash thoroughly after handling. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Take precautionary measures against static discharges. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or flames.

Hazards Identification
【Ingestion】May cause irritation of the digestive tract.
【Inhalation】Causes respiratory tract irritation.
【Skin】Causes severe burns.
【Eyes】Causes severe eye burns.
【Hazards】When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】R 21/22 34
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】2735

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Poison Class】4 (Substances and products that must be considered harmful)

Fire Fighting Measures
【Flash Point】75
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode when heated. Extinguishing media: Use water spray to cool fire-exposed containers. Cool containers with flooding quantities of water until well after fire is out. In case of fire, use water spray, dry chemical, carbon dioxide, or alcohol-resistant foam.
【Fire Potential】Combustible material: may burn but does not ignite ily.

Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Provide ventilation.

Stability and Reactivity
【Disposal Code】5
【Incompatibilities】Acids, acid chlorides, acid anhydrides, carbon dioxide, strong oxidizing agents.
【Stability】Stable under normal temperatures and pressures.
【Decomposition】Nitrogen oxides, carbon monoxide, carbon dioxide.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.

Transport Information
【UN Number】2735
【Hazard Class】8
【Packing Group】I; II; III
【HS Code】2921 49 80