Product Identification
【Product Name】3-Amino-4-chlorobenzotrifluoride
【Synonyms】Azoene Fast Orange RD；3-氨基-4-氯三氟甲苯
【CAS】121-50-6
【Formula】C7H5ClF3N
【Molecular Weight】195.57
【EINECS】204-475-7
【RTECS】XU5775000
【RTECS Class】Other
【Beilstein/Gmelin】879910
【Beilstein Reference】4-12-00-01852
【EC Class】irritant

Physical and Chemical Properties
【Appearance】Clear faint yellow to yellow liquid. Penetrating odor.
【Solubility in water】Insoluble
【Melting Point】10℃
【Boiling Point】208℃
【Vapor Pressure】0.22 (25℃)
【Density】1.42 g/cm3
【pKa/pKb】12.57 (pKb)
【Partition Coefficient】3.76
【Heat Of Vaporization】44.4 kJ/mol
【Refractive Index】1.50 (20℃)

First Aid Measures
【Ingestion】If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Induce vomiting by giving one teaspoon of Syrup of Ipecac.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage
【Storage】Keep away from sources of ignition. Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container.
【Handling】Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.

Hazards Identification
【Inhalation】May cause cyanosis, characterized by bluish-colored skin. Causes respiratory tract irritation.
【Skin】Causes skin irritation. May be absorbed through the skin in harmful amounts.
【Eyes】Causes eye irritation.
【Ingestion】Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
【Hazards】Containers may explode when heated.
【EC Risk Phrase】R 23/24/25 36/38
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】3082

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron. Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】Prolonged exposure may produce a narcotic effect. Prolonged or repeated exposure may cause nausea, dizziness, and headache.

Fire Fighting Measures
【Flash Point】80℃
【Autoignition】>560℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
【Fire Potential】May burn but does not ignite ily.

Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Scoop up with a nonsparking tool, then place into a suitable container for disposal.

Stability and Reactivity
【Incompatibilities】Acids and oxidizing agents.
【Stability】Stable under normal temperatures and pressures.
【Decomposition】Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.

Transport Information
【UN Number】3082
【Hazard Class】9
【Packing Group】III
【HS Code】2921 43 00