Product Identification
【Product Name】Trimethylsilyl N-trimethylsilylacetamidate ;N,O-双三甲基硅基乙酰胺
【Synonyms】N-Trimethylsilyl-1-trimethylsilyloxyethanimine
【CAS】10416-59-8
【Formula】C8H21NOSi2
【Molecular Weight】203.43
【EINECS】233-892-7
【RTECS】AK3000000
【RTECS Class】Tumorigen
【Beilstein/Gmelin】1306669
【EC Class】flammable, harmful, corrosive
Physical and Chemical Properties
【Appearance】Light yellow liquid.
【Solubility in water】Insoluble
【Melting Point】24℃
【Boiling Point】162℃
【Vapor Pressure】3 (25℃)
【Density】0.82 g/cm3
【pKa/pKb】8.18 (pKb)
【Partition Coefficient】3.16
【Heat Of Vaporization】38.2
【Refractive Index】1.42 (20℃)
First Aid Measures
【Ingestion】If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and Storage
【Storage】Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or flames.
Hazards Identification
【Ingestion】The toxicological properties of this substance have not been fully investigated.
【Inhalation】May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated.
【Skin】No information regarding skin irritation and other potential effects was found.
【Eyes】No information regarding eye irritation and other potential effects was found.
【Hazards】Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will sp along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】R 10 14 22 34
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】2920
Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Fire Fighting Measures
【Flash Point】66℃
【Fire Fighting】Small Fires: Dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Large Fires: Water spray, fog or alcohol-resistant foam.
【Fire Potential】Flammable/combustible material. May be ignited by heat, sparks or flames.
Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. A vapor suppressing foam may be used to reduce vapors.
Stability and Reactivity
【Disposal Code】1
【Stability】Stable under normal temperatures and pressures.
【Incompatibilities】Strong oxidizing agents - strong acids - moist,air or water.
【Decomposition】Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen, silicon oxide.
【Combustion Products】Fire will produce irritating, corrosive and/or toxic gases.
Transport Information
【UN Number】2920
【Hazard Class】8
【Packing Group】I; II
【HS Code】2931 00 95