Product Identification
【Product Name】2-Aminophenetole
【Synonyms】o-Phenetidine；邻乙氧基苯胺
【CAS】94-70-2
【Formula】C8H11NO
【Molecular Weight】137.18
【EINECS】202-356-4
【RTECS】SI6465300
【RTECS Class】Other
【Merck】12,7372
【Beilstein/Gmelin】637069
【Beilstein Reference】4-13-00-00807
【EC Index Number】612-039-00-6
【EC Class】Toxic; Danger of cumulative effects

Physical and Chemical Properties
【Appearance】Reddish brown oily liquid.
【Solubility in water】Insoluble
【Melting Point】-4℃
【Boiling Point】229℃
【Vapor Pressure】0.061 (25℃)
【Density】1.0508 g/cm3 (20℃)
【Partition Coefficient】1.62
【Heat Of Vaporization】46.9 kJ/mol
【Usage】Production of dyes.
【Vapor Density】4.73
【Refractive Index】1.5545 (20℃)

First Aid Measures
【Ingestion】If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage
【Storage】Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or flames.

Hazards Identification
【Ingestion】May cause irritation of the digestive tract.
【Inhalation】Inhalation of vapors may cause irritation.
【Skin】May cause skin irritation. Absorbed through the skin.
【Eyes】May cause eye irritation.
【Hazards】When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】R 23/24/25 33
【EC Safety Phrase】S 28 36/37 45
【UN (DOT)】2311

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Fire Fighting Measures
【Flash Point】80℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Containers may explode when heated. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
【Fire Potential】This chemical is probably combustible.

Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.

Stability and Reactivity
【Disposal Code】9
【Incompatibilities】Oxidizing agents
【Stability】Stable under normal temperatures and pressures. Substance may under color change upon exposure to light and air.
【Decomposition】Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.

Transport Information
【UN Number】2311
【Hazard Class】6.1
【Packing Group】III
【HS Code】2922 22 00