Product Identification
【Product Name】2,5-Diaminobenzenesulfonic acid
【Synonyms】p-Phenylenediamine-2-sulfonic acid ；2,5-二氨基苯磺酸
【CAS】88-45-9
【Formula】C6H8N2O3S
【Molecular Weight】188.2
【EINECS】201-832-9
【RTECS】DB5900100
【RTECS Class】Mutagen
【Beilstein/Gmelin】2970398
【Beilstein Reference】4-14-00-02771
Physical and Chemical Properties
【Appearance】Violet powder.
【Solubility in water】Very soluble
【Melting Point】298~300 ℃
【Boiling Point】500℃
【pKa/pKb】8.83 (pKb)
First Aid Measures
【Ingestion】Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and Storage
【Storage】Keep container closed when not in use. Corrosives area.
【Handling】Use only in a well ventilated area. Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes.
Hazards Identification
【Inhalation】Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause cardiac abnormalities. May cause systemic effects. Exposure may produce metabolic acidosis. Inhalation at high concentrations may cause CNS depression and asphixiation.
【Skin】Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.
【Eyes】Causes eye burns. May cause chemical conjunctivitis and corneal damage.
【Ingestion】Causes gastrointestinal tract burns. May cause systemic toxicity with acidosis. May cause perforation of the digestive tract. May cause cardiac disturbances. May cause central nervous system effects. May cause systemic effects.
【Hazards】When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【UN (DOT)】2585
Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】Effects may be delayed.
Fire Fighting Measures
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Use water spray to cool fire-exposed containers. Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray.
【Fire Potential】Combustible material: may burn but does not ignite ily.
Accidental Release Measures
【Small spills/leaks】Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
Stability and Reactivity
【Incompatibilities】Oxidizing agents.
【Stability】Stable under normal temperatures and pressures.
【Decomposition】Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide, nitrogen.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.
Transport Information
【UN Number】2585
【Hazard Class】8
【Packing Group】III