Product Identification
【Product Name】2-Methyl-1,3-benzenediol 2,6-二羟基甲苯
【Synonyms】2,6-Dihydroxytoluene
【CAS】608-25-3
【Formula】C7H8O2
【Molecular Weight】124.14
【EINECS】210-155-8
【RTECS】VH2009500
【RTECS Class】Other
【Beilstein/Gmelin】2042177
【Beilstein Reference】4-06-00-05877
【EC Class】toxic, irritant
Physical and Chemical Properties
【Appearance】Beige crystals.
【Solubility in water】Slightly soluble
【Melting Point】120 - 122
【Boiling Point】264
【Vapor Pressure】0.007 (25 C)
【pKa/pKb】9.80 (pKa)
【Partition Coefficient】1.22
【Heat Of Vaporization】51.9 kJ/mol
First Aid Measures
【Ingestion】Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth respiration if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and Storage
【Storage】Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Hazards Identification
【Inhalation】Causes respiratory tract irritation. Can produce delayed pulmonary edema.
【Skin】Causes skin irritation. May cause dermatitis.
【Eyes】Causes eye irritation. May cause chemical conjunctivitis.
【Ingestion】Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
【Hazards】Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】R 25 36/37/38
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】2811
Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】Effects may be delayed.
Fire Fighting Measures
【Flash Point】130
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Potential】Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release Measures
【Small spills/leaks】Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Stability and Reactivity
【Incompatibilities】Acid chlorides, acid anhydrides, oxidizing agents.
【Stability】Stable at room temperature in closed containers under normal storage and handling conditions.
【Decomposition】Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.
Transport Information
【UN Number】2811
【Hazard Class】6.1
【Packing Group】I; II; III
【HS Code】2907 29 00