Product Identification
【Product Name】Acid Red 2  甲基红
【Synonyms】4-(2-Carboxyphenylazo)-N,N-dimethylaniline
【CAS】493-52-7
【Formula】C15H15N3O2
【Molecular Weight】269.31
【EINECS】207-776-1
【RTECS】DG8960000
【RTECS Class】Tumorigen; Mutagen
【Merck】12,6199
【Beilstein/Gmelin】750102
【Beilstein Reference】4-16-00-00504

Physical and Chemical Properties
【Appearance】Glistening, violet crystals from toluene.
【Solubility in water】Insoluble
【Melting Point】178~182℃
【Density】1.31 g/cm3
【pKa/pKb】2.5 (pKa)
【Usage】As indicator in 0.1% Alcoholic soln, ph: 4.4 Red, 6.2 Yellow, used for titrating nh3, weak organic bases, eg, alkaloids, not suitable for organic acids, except oxalic & picric acid.

First Aid Measures
【Ingestion】Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
【Skin】Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage
【Storage】

Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with skin and eyes. Avoid ingestion and inhalation.

Hazards Identification
【Inhalation】May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
【Skin】May cause skin irritation.
【Eyes】Contact may cause transient eye irritation. This product contains an anionic dye. Similar dyes have not caused injury to the cornea or conjunctiva in documented exposure cases with human or rabbit eyes.
【Ingestion】May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
【EC Safety Phrase】S 22 24/25
【UN (DOT)】1230

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】Substance may have carcinogenic potential.
【Poison Class】4 (Substances and products that must be considered harmful)

Fire Fighting Measures
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustion generates toxic fumes. Extinguishing media: For small fires, use water spray, dry chemical, carbon dioxide or chemical foam.
Accidental Release Measures
【Small spills/leaks】Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity
【Disposal Code】3
【Stability】Stable under normal temperatures and pressures. Materials containing similar functional groups can decompose at elevated temperatures.
【Incompatibilities】Strong oxidizing agents.
【Decomposition】Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.

Transport Information
【UN Number】1230
【HS Code】2927 00 00