Product Identification
【Product Name】2-Fluorobenzyl bromide
【Synonyms】o-Fluorobenzyl bromide ；邻氟溴苄
【CAS】446-48-0
【Formula】C7H6BrF
【Molecular Weight】189.02
【EINECS】207-169-1
【Beilstein/Gmelin】1099894
【Beilstein Reference】4-05-00-00830

Physical and Chemical Properties
【Appearance】Clear light brown liquid.
【Boiling Point】84℃
【Density】1.567 g/cm3
【Vapor Density】6.52
【Refractive Index】1.55 (20℃)

First Aid Measures
【Ingestion】Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration.
【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.

Handling and Storage
【Storage】Keep away from heat, sparks, and flame. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
【Handling】Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not allow contact with water. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or flames. Keep from contact with moist air and steam.

Hazards Identification
【Inhalation】Causes respiratory tract irritation. Can produce delayed pulmonary edema. Inhalation at high concentrations may cause CNS depression and asphixiation.
【Skin】Causes skin irritation. May cause dermatitis. May cause cyanosis of the extremities.
【Eyes】Produces irritation, characterized by a burning sensation, redness, tearing, inflammation, and possible corneal injury. Lachrymator. May cause chemical conjunctivitis.
【Ingestion】May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
【Hazards】When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】R 34 36
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】2810

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】Effects may be delayed.

Fire Fighting Measures
【Flash Point】82℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible Liquid. Water hydrolyzes material liberating acidic gas which in contact with metal surfaces can generate flammable and/or explosive hydrogen gas. Extinguishing media: Use water spray to cool fire-exposed containers. DO NOT USE WATER! Do NOT get water inside containers. In case of fire, use carbon dioxide, dry chemical powder or appropriate foam.
【Fire Potential】Combustible material: may burn but does not ignite ily.

Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Do not get water inside containers.

Stability and Reactivity
【Incompatibilities】Oxidizing agents, bases, alcohols, amines, steel, moisture, water.
【Stability】Stable at room temperature in closed containers under normal storage and handling conditions. Reacts with water to form toxic fumes.
【Decomposition】Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride, hydrogen bromide.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.

Transport Information
【UN Number】2810
【Hazard Class】6.1
【Packing Group】I; II; III