Product Identification
【Product Name】3-(Aminomethyl)pyridine
【Synonyms】Picolamine ;3-氨甲基吡啶
【CAS】3731-52-0
【Formula】C6H8N2
【Molecular Weight】108.14
【EINECS】223-091-0
【Beilstein/Gmelin】108056
【Beilstein Reference】5-22-09-00301
【EC Class】corrosive
Physical and Chemical Properties
【Appearance】Clear, colorless liquid.
【Solubility in water】Very soluble
【Melting Point】-21℃
【Boiling Point】226℃
【Vapor Pressure】0.1 (25℃)
【Density】1.0712 g/cm3 (20℃)
【pKa/pKb】8.34 (pKa)
【Partition Coefficient】-.4
【Heat Of Vaporization】46.3 kJ/mol
【Usage】Medication.
【Refractive Index】1.552 (20℃)
First Aid Measures
【Ingestion】Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. SPEEDY ACTION IS CRITICAL!
Handling and Storage
【Storage】Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Corrosives area.
【Handling】Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Hazards Identification
【Ingestion】Causes gastrointestinal tract burns.
【Inhalation】Causes chemical burns to the respiratory tract.
【Skin】Causes skin burns.
【Eyes】Causes eye burns.
【Hazards】When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】R 34
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】3267
Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Fire Fighting Measures
【Flash Point】100℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
【Fire Potential】Combustible material: may burn but does not ignite ily.
Accidental Release Measures
【Small spills/leaks】Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment.
Stability and Reactivity
【Disposal Code】5
【Stability】Stable under normal temperatures and pressures.
【Incompatibilities】Strong oxidizing agents and strong acids
【Decomposition】Nitrogen oxides, carbon monoxide, carbon dioxide.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.
Transport Information
【UN Number】3267
【Hazard Class】8
【Packing Group】I; II; III
【HS Code】2933 39 99