Product Identification
【Product Name】2-Fluorophenol
【Synonyms】邻氟苯酚
【CAS】367-12-4
【Formula】C6H5FO
【Molecular Weight】112.1
【EINECS】206-681-2
【RTECS】SL4530000
【RTECS Class】Other
【Beilstein/Gmelin】1905112
【Beilstein Reference】4-06-00-00770
【EC Class】irritant

Physical and Chemical Properties
【Appearance】Clear, yellow liquid.
【Solubility in water】Slightly soluble
【Melting Point】16℃
【Boiling Point】151℃
【Density】1.2172 g/cm3 (16℃)
【pKa/pKb】8.71 (pKa)
【Refractive Index】1.5112 (15.8℃)

First Aid Measures
【Ingestion】not available, a glass of milk, or beaten egg whites and IMMEDIATELY transport victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, assure that the victim's airway is and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital.
【Inhalation】IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.
【Skin】IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas.
【Eyes】First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Handling and Storage
【Storage】Store in a flammables-area.
【Handling】All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification
【Inhalation】Vapors may cause dizziness or suffocation. May cause irritation or burns.
【Skin】May cause irritation or burns.
【Eyes】See Skin.
【Hazards】Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will sp along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】R 10 21/22 34
【EC Safety Phrase】S 26 36/37/39 45
【UN (DOT)】1993

Exposure Controls/Personal Protection
【Personal Protection】If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves.
【Respirators】Wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter.
【Exposure Effects】The toxological properties of this substance have not been fully investigated.

Fire Fighting Measures
【Flash Point】46℃
【Fire Fighting】This compound is not very flammable but any fire involving this compound may produce dangerous vapors. You should evacuate the area. All firefighters should wear full-body protective clothing and use self-contained breathing apparatuses. You should extinguish any fires involving this chemical with a dry chemical, carbon dioxide, foam, or halon extinguisher.
【Fire Potential】HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Accidental Release Measures
【Small spills/leaks】Should a spill occur while you are handling this chemical, you should dampen the solid spill material with alcohol, then transfer the dampened material to a suitable container. Use absorbent paper dampened with alcohol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution. Do not reenter the contaminate area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Stability and Reactivity
【Disposal Code】2
【Stability】Stable under normal temperatures and pressures.
【Decomposition】Will form the following upon decomposition: carbon monoxide, carbon dioxide, hydrogen fluoride.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.

Transport Information
【UN Number】1993
【Hazard Class】3
【Packing Group】I; II; III
【HS Code】2908 10 00