Product Identification
【Product Name】2-Biphenylyl bromide
【Synonyms】o-Bromobiphenyl 2-溴联苯
【CAS】2052-07-5
【Formula】C12H9Br
【Molecular Weight】233.11
【EINECS】218-141-3
【Beilstein/Gmelin】1863156
【Beilstein Reference】4-05-00-01818

Physical and Chemical Properties
【Appearance】Clear liquid.
【Solubility in water】Insoluble
【Melting Point】2℃
【Boiling Point】297℃
【Vapor Pressure】0.0025 (25℃)
【Density】1.2766 g/cm3 (20℃)
【Partition Coefficient】4.63
【Heat Of Vaporization】51.5 kJ/mol
【Refractive Index】1.6248 (25℃)

First Aid Measures
【Ingestion】DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician.
【Inhalation】IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.
【Skin】IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.
【Eyes】First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Handling and Storage
【Storage】Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
【Handling】All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification
【Inhalation】Inhalation of material may be harmful.
【Skin】Contact may cause burns.
【Eyes】See Skin.
【Hazards】Containers may explode when heated.
【EC Safety Phrase】S 24/25
【UN (DOT)】2315

Exposure Controls/Personal Protection
【Personal Protection】Wear appropriate protective gloves, clothing and ggles.
【Respirators】Wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter.
【Exposure Effects】The toxological properties of this substance have not been fully investigated.

Fire Fighting Measures
【Flash Point】134
【Fire Fighting】Fires involving this material should be controlled using a dry chemical carbon dioxide or Halon extinguisher.
【Fire Potential】This material is probably combustible.

Accidental Release Measures
【Small spills/leaks】If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Stability and Reactivity
【Disposal Code】3
【Stability】No data.
【Incompatibilities】Sensitive to light.
【Combustion Products】Fire may produce irritating, corrosive and/or toxic gases.

Transport Information
【UN Number】2315
【Hazard Class】9
【Packing Group】II
【HS Code】2903 69 90