Product Identification(靛红酸酐安全技术说明书)
【Product Name】N-Carboxyanthranilic anhydride
【Synonyms】Isato acid anhydride
【CAS】118-48-9
【Formula】C8H5NO3
【Molecular Weight】163.13
【EINECS】204-255-0
【RTECS】DM3100000
【RTECS Class】Reproductive Effector
【Beilstein/Gmelin】136786
【Beilstein Reference】4-27-00-03330
【EC Index Number】607-250-00-5
【EC Class】Irritant; Sensitising

Physical and Chemical Properties
【Appearance】Prism from alcohol or glacial acetic acid; crystals from alcohol or dioxane.
【Solubility in water】Slightly soluble
【Melting Point】164℃
【Boiling Point】385℃
【Density】1.55 g/cm3
【pKa/pKb】8.91 (pKa)
【Partition Coefficient】.91
【Usage】Intermediate for polymer curing agents, anthranilic esters, heterocyclic compd, & benzyne.
【Vapor Density】5.6

First Aid Measures
【Ingestion】Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage
【Storage】Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
【Handling】Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Do not allow contact with water. Wash clothing before reuse. Keep from contact with moist air and steam.

Hazards Identification
【Inhalation】Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
【Skin】Causes skin irritation.
【Eyes】Causes eye irritation.
【Ingestion】Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
【EC Risk Phrase】R 36 43
【EC Safety Phrase】S 24 26 37
【UN (DOT)】3335

Exposure Controls/Personal Protection
【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate gloves to prevent skin exposure.
Clothing: Wear appropriate clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】Irritating to eyes, respiratory system and skin. The toxicological properties of this material have not been investigated.
【Poison Class】5

Fire Fighting Measures
【Autoignition】>600℃
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. Do NOT get water inside containers. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Accidental Release Measures
【Small spills/leaks】Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.

Stability and Reactivity
【Disposal Code】4
【Incompatibilities】Oxidizing agents.
【Stability】Stable at room temperature in closed containers under normal storage and handling conditions.
【Decomposition】Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.

Transport Information
【UN Number】3335
【HS Code】2934 99 90